Synthesis of Optically Active Oxymethylenehelicene Oligomers and Self-assembly Phenomena at a Liquid-Solid Interface
Title:
Synthesis of Optically Active Oxymethylenehelicene Oligomers and Self-assembly Phenomena at a Liquid-Solid Interface
ISBN:
9789811531927
Personal Author:
Edition:
1st ed. 2020.
Publication Information New:
Singapore : Springer Nature Singapore : Imprint: Springer, 2020.
Physical Description:
XII, 83 p. 67 illus., 59 illus. in color. online resource.
Series:
Springer Theses, Recognizing Outstanding Ph.D. Research,
Contents:
1. Introduction -- 2. Fibril Film Formation of Pseudoenantiomeric Oxymethylenehelicene Oligomers at the Liquid-Solid Interface -- 3. Mechanical Stirring Induces Heteroaggregate Formation and Self-assembly of Pseudoenantiomeric Oxymethylenehelicene Oligomers in Solution -- 4. Proximate Stochastic Chiral Symmetry Breaking by Racemic Oxymethylenehelicene Oligomers -- 5. Conclusions -- 6. Experimental Section.
Abstract:
In this book, the author demonstrates that double-helix formation and fibril film formation occur on solid surfaces as a result of the catalytic effect of the liquid-solid interface of the newly synthesized helicene oligomer. In addition, he shows that the double helix produced at the liquid-solid interface can be diffused into a solution to form a self-assembling material by means of mechanical stirring. Both types of formation are new chemical phenomena unique to liquid-solid interfaces not found in solutions. Detailed results are provided for new chemical reactions at liquid-solid interfaces, and gleaned from experiments performed using synthetic organic molecules. The book offers a useful reference guide to elucidating reaction mechanisms for researchers whose work involves chemical phenomena at a liquid-solid interface. .
Added Corporate Author:
Language:
English