Hyperspherical Harmonics Applications in Quantum Theory
Başlık:
Hyperspherical Harmonics Applications in Quantum Theory
ISBN:
9789400923232
Personal Author:
Edition:
1st ed. 1989.
Yayın Bilgileri:
Dordrecht : Springer Netherlands : Imprint: Springer, 1989.
Fiziksel Tanımlama:
XVI, 256 p. online resource.
Series:
Reidel Texts in the Mathematical Sciences ; 5
Contents:
Harmonic polynomials -- Generalized angular momentum -- Gegenbauer polynomials -- Fourier transforms in d dimensions -- Fock's treatment of hydrogenlike atoms and its generalization -- Many-dimensional hydrogenlike wave functions in direct space -- Solutions to the reciprocal-space Schrödinger equation for the many-center Coulomb problem -- Matrix representations of many-particle Hamiltonians in hyper spherical coordinates -- Iteration of integral forms of the Schrödinger equation -- Symmetry-adapted hyperspherical harmonics -- The adiabatic approximation -- Appendix A: Angular integrals in a 6-dimensional space -- Appendix B: Matrix elements of the total orbital angular momentum operator -- Appendix C: Evaluation of the transformation matrix U -- Appendix D: Expansion of a function about another center -- References.
Abstract:
where d 3 3)2 ( L x - -- i3x j3x j i i>j Thus the Gegenbauer polynomials play a role in the theory of hyper spherical harmonics which is analogous to the role played by Legendre polynomials in the familiar theory of 3-dimensional spherical harmonics; and when d = 3, the Gegenbauer polynomials reduce to Legendre polynomials. The familiar sum rule, in 'lrlhich a sum of spherical harmonics is expressed as a Legendre polynomial, also has a d-dimensional generalization, in which a sum of hyper spherical harmonics is expressed as a Gegenbauer polynomial (equation (3-27»: The hyper spherical harmonics which appear in this sum rule are eigenfunctions of the generalized angular monentum 2 operator A , chosen in such a way as to fulfil the orthonormality relation: VIe are all familiar with the fact that a plane wave can be expanded in terms of spherical Bessel functions and either Legendre polynomials or spherical harmonics in a 3-dimensional space. Similarly, one finds that a d-dimensional plane wave can be expanded in terms of HYPERSPHERICAL HARMONICS xii "hyperspherical Bessel functions" and either Gegenbauer polynomials or else hyperspherical harmonics (equations ( 4 - 27) and ( 4 - 30) ) : 00 ik·x e = (d-4)!!A~oiA(d+2A-2)j~(kr)C~(~k'~) 00 (d-2)!!I(0) 2: iAj~(kr) 2:Y~ (["2k)Y (["2) A A=O ). l). l)J where I(O) is the total solid angle. This expansion of a d-dimensional plane wave is useful when we wish to calculate Fourier transforms in a d-dimensional space.
Ek Kurum Yazarı:
Dil:
English