Supramolecular chemistry
Başlık:
Supramolecular chemistry
ISBN:
9780128151105
Edition:
First edition.
Yayın Bilgileri:
Cambridge, MA : Academic Press, an imprint of Elsevier, 2018.
Fiziksel Tanımlama:
1 online resource : illustrations (some color)
Series:
Advances in inorganic chemistry ; volume 71
Advances in inorganic chemistry ; v. 71.
Contents:
Front Cover; Supramolecular Chemistry; Copyright; Contents; Contributors; Preface; Feature Article; Chapter One: From Coordination Chemistry to Adaptive Chemistry; 1. From Discrete Molecules to Self-Organized Molecular Assemblies; 2. From Self-Organization to Constitutional Dynamics and Adaptation; 2.1. Self-Organization and Self-Organization by Design; 2.2. Supramolecular Architectures Built Around a Single Type of Metal Ion and Relying on a Single Steric Program; 2.2.1. Supramolecular Square Grid-Like Complexes; 2.2.2. Supramolecular Linear and Circular Helical Complexes
2.3. Supramolecular Architectures Resulting From Two or More Informational Programs2.3.1. Crossover Between Two Steric Programs; 2.3.1.1. Metallosupramolecular Cage-Like and Ladder-Like Coordination Architectures; 2.3.1.2. Metallosupramolecular Rack-Like and Rectangular Grid-Like Coordination Architectures; 2.3.1.3. Supramolecular Heteroduplex Helical Complexes; 2.3.2. From Robustness to Homo-S and Hetero-Self-Sorting Processes; 2.3.3. Dominant/Recessive Behaviors Between Two Steric Programs; 2.4. Supramolecular Architectures Built Around Multiple Steric Subprograms
3. Constitutional Dynamics and Adaptation3.1. Supramolecular Constitutional Dynamics; 3.2. Motional Dynamic Chemistry; 3.2.1. Structural Features of Polyheterocyclic Strands and Related Metal Complexes; 3.2.2. Extension/Contraction Motions of Helical Ligands; 3.2.3. Extension/Contraction Motions of Linear Ligands; 3.2.4. Extension/Contraction Motions in Mixed Linear/Helical Ligands; 3.2.5. Shape Changes Induced by the Interconversion of Different Metallosupramolecular Architectures; 3.2.6. Dynamic Switching Devices; 4. CDC and Constitutional Dynamic Networks
4.1. Combining Constitutional Dynamics at the Supramolecular and Molecular Level4.1.1. Implementation of CDC in Coordination Chemistry; 4.1.2. Applications of CDC: The Example of Metallodynamers; 4.2. Constitutional Dynamic Networks; 4.2.1. Implementation of Constitutional Dynamic Networks in Coordination Chemistry; 4.2.2. Coevolution in Constitutional Dynamic Networks; 4.2.3. Constitutional Dynamic Networks as Information Devices; 4.2.4. Toward More Complex Constitutional Dynamic Networks; 5. Toward Systems Chemistry; Acknowledgement; References
Chapter Two: A Journey From Solution Self-Assembly to Designed Interfacial Assembly1. Introduction; 2. From Coordination Chemistry to Metallosupramolecular Chemistry; 2.1. Coordination Chemistry as Molecular Recognition; 2.2. Metal-Binding Domains; 2.3. Metallosupramolecular Chemistry; 2.3.1. Partitioning Metal-Binding Domains in Polydentate Ligands; 2.3.2. Symmetrical Partitioning of Metal-Binding Domains in Helical Metallosupramolecules; 2.3.3. Asymmetrical Partitioning of Metal-Binding Domains in Helical Metallosupramolecules; 2.4. From Pure Compounds to Libraries
Abstract:
Supramolecular Chemistry, Volume 71, the latest release in the Advances in Inorganic Chemistry series presents timely and informative summaries on the current progress in a variety of subject areas within inorganic chemistry, ranging from bio-inorganic to solid state studies. This acclaimed serial features reviews written by experts in the field, serving as an indispensable reference to advanced researchers. In this volume, concise, authoritative reviews provide an up-to-date resource material for new investigators and established research personnel. Included references enable readers to pursue detail and development in each field. In addition, research chemists in other fields can use this serial to acquaint themselves with the latest experimental methods, techniques and computational applications within the field of inorganic reaction mechanisms.
Local Note:
Elsevier
Elektronik Erişim:
Full Text Available From Elsevier e-Books
Dil:
English